go to top scroll for more

Projects

Projects: Custom Search
Reference Number EP/T031174/1
Title Ionic-Liquid Mixtures: from Surface Structure to Catalytic Performance
Status Started
Energy Categories Not Energy Related 70%;
Other Power and Storage Technologies (Electric power conversion) 15%;
Other Power and Storage Technologies (Energy storage) 15%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Chemistry) 100%
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Dr JM Slattery
University of York
Award Type Standard
Funding Source EPSRC
Start Date 01 January 2021
End Date 30 June 2025
Duration 54 months
Total Grant Value £692,816
Industrial Sectors Chemical measurement
Region Yorkshire & Humberside
Programme NC : Physical Sciences
 
Investigators Principal Investigator Dr JM Slattery , University of York
  Other Investigator Professor D Bruce , University of York
Web Site
Objectives
Abstract Ionic liquids (ILs), with their unique combination of properties and wealth of potential applications, have captured the imagination of a large community of scientists in recent years. Fundamental studies on ILs have led to breakthroughs in our understanding and have enabled the development of ILs that are promising candidates for use in areas such as catalysis, carbon-capture and storage (CCS), biomass processing, as electrolytes in batteries, supercapacitors and dye-sensitised solar cells and more. This project aims to develop and utilise a wide range of experimental and computational methodologies to investigate the surface, and bulk, structure of IL mixtures that are currently poorly understood and consequently underutilised. We previously developed a novel technique that can probe liquid interfaces with direct chemical specificity, Reactive-Atom Scattering - Laser-Induced Fluorescence (RAS-LIF), and used it to detect H (or D)-containing functional groups at IL interfaces. We will extend its applicability to new chemical functionalities, in particular fluorinated species, by using high-energy Al-atoms as reactive probes of fluorinated functionality (on both cations and anions) at IL surfaces. This will be complemented by new capabilities for studying liquid surfaces by X-ray and neutron reflectivity under catalytically relevant conditions, and by bulk structure/property studies. The detailed understanding developed will lead to structure-property relationships in IL mixture systems that will be used in the final stages of the project in supported IL phase (SILP) catalysis and will support the deployment of new and bespoke functional ILs for catalysis in SILP systems. This ambitious project aims to cover the whole pipeline of IL development from preparation, to structural understanding, and then to industrially relevant applications.
Data

No related datasets

Projects

No related projects

Publications

No related publications

Added to Database 13/08/25