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Projects: Projects for Investigator
Reference Number EP/G004900/1
Title CATALYTIC PRODUCTION OF CYCLIC CARBONATES FROM WASTE CARBON DIOXIDE
Status Completed
Energy Categories Fossil Fuels: Oil Gas and Coal(CO2 Capture and Storage, CO2 capture/separation) 100%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Chemistry) 100%
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Professor M North
No email address given
Natural Sciences
Newcastle University
Award Type Standard
Funding Source EPSRC
Start Date 01 October 2008
End Date 30 September 2009
Duration 12 months
Total Grant Value £148,720
Industrial Sectors Chemicals
Region North East
Programme User-Led Research
 
Investigators Principal Investigator Professor M North , Natural Sciences, Newcastle University (100.000%)
Web Site
Objectives
Abstract The world is currently producing too much carbon dioxide and this is contributing to global warming. A significant amount of this carbon dioxide is produced at fixed sites including fossil fuel power stations, chemical plants and metal production sites. The aim of this proposal is to take this waste carbon dioxide and divert it away from atmospheric release to be used in the synthesis of cyclic carbonates which are themselves commercially important chemicals with a prospective market of up to30 million tonnes per annum. If fully implemented, this could reduce the UK's carbon dioxide emissions by about 2.5% per annum and generate significant wealth within the UK.To accomplish this transformation we will develop and exploit bimetallic aluminium complexes similar to those we have already published and show that they can be used successfully in a continuous flow reactor with ethylene oxide and carbon dioxide as reactant and ethylene carbonate as product. During this project, the structure of both the aluminium salen complex and the solid support will be optimized.In addition, a thorough analysis of the current and potential market for cyclic carbonates will be undertaken. This will concentrate on analysing the capabilities of the current manufacturers, determining the current and anticipated current demand and quantifying the availability of the ethylene oxide and other epoxides required as raw materials
Publications (none)
Final Report (none)
Added to Database 03/06/08