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Projects: Projects for Investigator
Reference Number GR/S85238/01
Title Discovery of new functional oxides by combinatorial methods
Status Completed
Energy Categories Not Energy Related 85%;
Hydrogen and Fuel Cells(Fuel Cells) 15%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Chemistry) 50%;
PHYSICAL SCIENCES AND MATHEMATICS (Metallurgy and Materials) 50%;
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Professor JA (John ) Kilner
No email address given
Materials
Imperial College London
Award Type Standard
Funding Source EPSRC
Start Date 01 October 2004
End Date 31 March 2008
Duration 42 months
Total Grant Value £281,841
Industrial Sectors Communications; Electronics; Energy; Manufacturing; Transport Systems and Vehicles
Region London
Programme Physical Sciences
 
Investigators Principal Investigator Professor JA (John ) Kilner , Materials, Imperial College London (100.000%)
  Industrial Collaborator Project Contact , Ceres Power Limited (0.000%)
Project Contact , University of Southampton (0.000%)
Project Contact , Morgan Electro Ceramics (0.000%)
Project Contact , Powerwave UK Ltd (0.000%)
Project Contact , Faraday: INSIGHT (Chemical Throughput) (0.000%)
Project Contact , Lucideon Ltd (0.000%)
Web Site
Objectives
Abstract This proposal intends using a new and recently commissioned combinatorial robot to prepare samples of functional oxide materials. The consortium s expertise lies in several areas of functional materials but we intend concentrating on:* Transport in oxides - both electronic and ionic. New electrode materials and new ionic conductors are required for high efficiency fuel cells.ferroelectric / paraelectric properties. New ferroelectric / paraelectric materials are required for voltage tuneable devices. In particular we require low loss materials.* Dielectric properties. New dielectrics are required in a wide range of applications from dielectric resonator materials with low loss and relative permittivities in the region 30, 80, and 150 to new gate dielectrics for transistors.The method used to conduct the search is novel and makes use of a purpose-built ink jet printer technique. This avoids any strain effects that may be associated with thin film methods. Such effects can cause difficulties when making measurements in compounds with complex permittivity, for example ferroelectrics and paraelectrics. The consortium has the means to produce the samples, possesses the characterisation equipment (XRD/EPMA/Raman/IR/SIMS) and has well developed plans for high throughput characterisation. Importantly, we also have clear plans on the measurement of function (Microwave dielectric loss, relative permittivity, electronic and ionic conductivity) on the samples produced by the robot.Finally, we will use our access to first class computing facilities to process the very large data sets that will be produced. We will make use of the technologies being developed for searching large data sets, such as genetic algorithm searches, inductive logic programming, and data modelling with neural networks. At first these tools will be used to extract meaning from the data but a future goal is to investigate to what extent the instrument can steer itself. The instrument will be a partofthe emerging UK Grid which will provide methods for accessing it remotely consistent with other Grid enabled instruments. The Grid also provides a paradigm for encapsulating the instrument as a general provider of data which can be trivially connected to data sinks on the Grid, such as other search tools, visualisation, teaching aids
Publications (none)
Final Report (none)
Added to Database 01/01/07