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Reference Number EP/H046313/1
Title Bio-inspired (Fe,Ni)S nano-catalysts for CO2 conversion
Status Completed
Energy Categories FOSSIL FUELS: OIL, GAS and COAL(CO2 Capture and Storage, CO2 capture/separation) 75%;
RENEWABLE ENERGY SOURCES(Solar Energy, Photovoltaics) 25%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Chemistry) 80%;
ENGINEERING AND TECHNOLOGY (Chemical Engineering) 20%;
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Dr NH De Leeuw
No email address given
University College London
Award Type Standard
Funding Source EPSRC
Start Date 01 May 2010
End Date 30 October 2013
Duration 42 months
Total Grant Value £1,138,877
Industrial Sectors Manufacturing
Region London
Programme Energy : Energy
Investigators Principal Investigator Dr NH De Leeuw , Chemistry, University College London (99.995%)
  Other Investigator Dr J Darr , Chemistry, University College London (0.001%)
Professor R Catlow , Chemistry, University College London (0.001%)
Dr G Hogarth , Chemistry, University College London (0.001%)
Dr KB Holt , Chemistry, University College London (0.001%)
Professor ES Fraga , Chemical Engineering, University College London (0.001%)
  Industrial Collaborator Project Contact , Johnson Matthey Technology Centre (0.000%)
Web Site
Abstract Despite the high thermodynamic stability of CO2, biological systems are capable of both activating the molecule and converting it into a range of organic molecules, all of which under moderate conditions. It is clear that, if we were able to emulate Nature and successfully convert CO2 into useful chemical intermediates without the need for extreme reaction conditions, the benefits would be enormous: One of the major gases responsible for climate change would become an important feedstock for the chemical and pharmaceutical industries!Iron-nickel sulfide membranes formed in the warm, alkaline springs on the Archaean ocean floor are increasingly considered to be the early catalysts for a series of chemical reactions leading to the emergence of life. The anaerobic production of acetate, formaldehyde, amino acids and the nucleic acid bases - the organic precursor molecules of life - are thought to have been catalyzed by small cubane (Fe,Ni)S clusters (for example Fe5NiS8), which are structurally similar to the surfaces of present day sulfide minerals such as greigite (Fe3S4) and mackinawite (FeS).Contemporary confirmation of the importance of sulfide clusters as catalysts is provided by a number of proteins essential to modern anaerobic life forms, such as ferredoxins, hydrogenases, carbon monoxide dehydrogenase (CODH) or acetyl-coenzyme A synthetase (ACS), all of which retain cubane (Fe,Ni)S clusters with a greigite-like local structure, either as electron transfer sites or as active sites to metabolise volatiles such as H2, CO and CO2.In view of the importance of (Fe,Ni)S minerals as catalysts for pre-biotic CO2 conversion, we propose employing a robust combination of state-of-the-art computation and experiment in a grand challenge to design, synthesise, test, characterise, evaluate and produce for scale-up novel iron-nickel sulfide nano-catalysts for the activation and chemical modification of CO2. The design of the (Ni,Fe)S nano-particles is inspired by theactive sites in modern biological systems, which are tailored to the complex redox processes in the conversion of CO2 to biomass.The scientific outcome of the Project will be the design and development of a new class of sulphide catalysts, tailored specifically to the reduction and conversion of CO2 into chemical feedstock molecules, followed by the fabrication of an automated pilot device. Specific deliverables include:i. Atomic-level understanding of the effect of size, surface structure andcomposition on stabilities, the redox properties and catalytic activities of (Fe,Ni)S nano-catalysts;ii. Development of novel synthesis methods of Fe-M-S nano-clusters and -particles with tailored catalytic properties (M = Ni and other promising transition metal dopants);iii. Rapid production and electro-catalytic screening of lead nano-catalysts for the activation/conversion of CO2;iv. Development and application of a new integrated design-synthesis-screening approach to produce effective nano-catalysts for desired reactions;v. Construction of a prototype device capable of catalysing low-temperature reactions of CO2 into products at typical low-voltages, that can be obtained from solar energy;vi. Identification of optimum process for scale-up in Stage 2, from the Economic, Environmental and Societal Impact evaluationThe target at the end-point of Stage 1 is the fabrication of a photo-electrochemical reactor capable of harvesting solar energy to (i) recover CO2 from carbon captureprocess streams, (ii) combine it with hydrogen, and (iii) catalyse the reaction into product. In Stage 2 of the project, the prototype will be developed into a scaled-up commercially viable device, using optimum catalyst(s) in terms of (i) reactivity/selectivity towards the desired reaction; (ii) economic impact; and (iii) environmental, ethical and societal considerations
Publications (none)
Final Report (none)
Added to Database 25/03/10