Collaborative Research Opportunities in Energy with South Africa: Ab-Initio development and testing of fuel cell catalysts

Completed

Hydrogen and Fuel Cells(Fuel Cells, Mobile applications)

Basic and strategic applied research

PHYSICAL SCIENCES AND MATHEMATICS (Chemistry)

Not Cross-cutting

Prof A Kucernak
Chemistry
Imperial College London

Standard

EPSRC

05 October 2009

04 October 2013

48 months

£618,602

Energy

London

Energy : Energy

Prof A Kucernak, Chemistry, Imperial College London

Dr T Albrecht, Chemistry, Imperial College London
Professor NP Brandon, Earth Science and Engineering, Imperial College London

Dr D Kramer, Faculty of Engineering and the Environment, University of Southampton

Project Contact, Johnson Matthey Technology Centre
Project Contact, Mintek, South Africa
Project Contact, University of Cape Town

The proposers have been closely involved in meetings with the key groups leading a new South African programme in catalysis. This proposal has emerged from these discussions, and is timely given the imminent launch of the ten year strategic programme in South Africa, and the establishment of the new Catalysis Competence Centre at the University of Cape Town and Mintek. It is closely aligned to the goals of the "Collaborative Research Opportunities in Energy with South Africa" call.Oxygen reduction may be considered one of the "Grand Challenges" faced by us in energy research. Success in this area may lead to at least a 20% improvement in the efficiency of low temperature fuel cell systems and a significant cost reduction in fuel cells. The most active and stable catalyst for oxygen reduction in low temperature fuel cells is platinum, which unfortunately is somewhat rare. Consequently, platinum particles with ever decreasing diameter are employed today to providethe largest amount of catalytic surface per precious metal atom. Yet nano-scale platinum particles are less stable than bulk platinum and provide inferior catalytic activity. Indeed, bulk platinum shows an oxygen reduction activity per surface atom which is about 20-times higher than for an atom on a 2.5 nm particle. If we could achieve the same surface reactivity for the oxygen reduction reaction in these ultra small particles as for bulk platinum, then we would be able to produce fuel cellpowered cars with no more precious metal in them than the amount which is in the catalytic exhaust system of today's cars.The engineering of binary core-shell nanoparticles is a promising approach to achieve this goal. These catalysts consist of a core of inexpensive metal surrounded by a "shell" of precious metal. An obvious advantage of this approach is the reduction in required platinum as all the platinum is restricted to the surface of the particles. Additionally, structural and electronic properties of this surface platinum are altered potentially leading to improved stability and activity. The preparation of a few examples of particles with different cores is reported in the literature with indications of superior catalytic activity. However little is known about their thermodynamic stability, nor the likely composition of the best core-shell catalysts.The aim of this project is to produce a range of stable core-shell catalyst which have a platinum mass activitywhich is twenty times higher than the mass activity for a platinum catalyst of the same particle size. Such an improvement would allow a near 20-fold drop in platinum requirement in current fuel cells and thus significantly surpass the goals of the Department of Energy (USA) in required catalyst performance. Our approach is to link together both computational materials discovery with advanced testing procedures to efficiently map a large range of possible materials. Synthesis and testing of asmall number of catalysts will be utilised to assure us that the computational search approach is operating efficiently and accurately.The proposal benefits from the significant research input being expended by our South African partners. They will match the manpower requested for this proposal (one PDRA, one PhD and staff time), and will take on a significant portion of the research effort funded through the South African Hydrogen Catalysis Competence Centre at the University of Capetown andMintek

16/06/09