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Projects: Projects for Investigator
Reference Number EP/M013839/1
Title Understanding CO2 Reduction Catalysts
Status Completed
Energy Categories Not Energy Related 20%;
Fossil Fuels: Oil Gas and Coal(CO2 Capture and Storage, CO2 capture/separation) 80%;
Research Types Basic and strategic applied research 100%
Science and Technology Fields PHYSICAL SCIENCES AND MATHEMATICS (Chemistry) 50%;
PHYSICAL SCIENCES AND MATHEMATICS (Metallurgy and Materials) 50%;
UKERC Cross Cutting Characterisation Not Cross-cutting 100%
Principal Investigator Dr DJ Payne
No email address given
Materials
Imperial College London
Award Type Standard
Funding Source EPSRC
Start Date 05 January 2015
End Date 03 January 2017
Duration 24 months
Total Grant Value £295,230
Industrial Sectors Manufacturing
Region London
Programme Manufacturing : Manufacturing
 
Investigators Principal Investigator Dr DJ Payne , Materials, Imperial College London (99.999%)
  Other Investigator Dr CK Williams , Chemistry, Imperial College London (0.001%)
Web Site
Objectives
Abstract The need to monitor the synthesis and catalytic performance of materials in-situ and in-operando is of critical importance if we are to find where the barriers to increased catalytic efficiency are, and understand and develop methodologies to circumvent them. Photoelectron spectroscopy (PES) is a widely used multidisciplinary technique widely used to study the composition and chemistry of material surfaces. It is an UHV technique, meaning that it is not possible to investigate the solid-gas interface and consequential reactivity. High-pressure photoelectron spectroscopy (HiPPES) is at the forefront of advanced surface characterization techniques as it now allows the measurement of surface chemistry and physics at near-environmental pressures that are highly relevant for technological applications. Whereas standard photoelectron spectroscopy is performed in the UHV (10-9 mbar) pressure range, HiPPES measurements are performed at pressures greater than 10 mbar. This means that surface reactions can be monitored under highly relevant conditions (e.g. as a function of pressure, temperature, humidity, acidity); in stark contrast to the strongly reducing conditions of a conventional spectrometer which not only provide no dynamic information, but may also actually alter the surface chemistry of the system under study. We aim to use the HiPPES technique to the surface chemistry taking place between copper nanoparticles and CO2. By monitoring the interactions of the gas-solid interface we aim to determine the nature of catalytic active sites, and propose evidence-based mechanisms for the reduction of CO2 on copper. We will study the surface chemistry as a function of temperature, co-adsorbates (such as water and O2) and pH. We hope to understand these nanocatalysts in greater detail, to raise the catalytic efficiency, or to discover new catalysts, thereby enabling the economic viability of carbon capture and utilisation technologies
Publications (none)
Final Report (none)
Added to Database 21/01/15