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Investigation of the 'Dioxin Memory Effect' in Waste lncinerator Flue Gas Systems

Reference Number
GR/R98549/01
Title
Investigation of the 'Dioxin Memory Effect' in Waste lncinerator Flue Gas Systems
Status
Completed
Energy Categories
Renewable Energy Sources(Bio-Energy, Applications for heat and electricity)
Research Types
Basic and strategic applied research
Science and Technology Fields
PHYSICAL SCIENCES AND MATHEMATICS (Chemistry)
UKERC Cross Cutting Characterisation
Not Cross-cutting
Principal Investigator
Professor P Williams
Energy Resources Research Unit
University of Leeds
Award Type
Standard
Funding Source
EPSRC
Start Date
22 January 2003
End Date
21 January 2006
Duration
36 months
Total Grant Value
£222,800
Industrial Sectors
Tools; technologies & methods
Region
Yorkshire & Humberside
Programme
Chemical Engineering Responsive -- Materials, Mechanical and Medical Eng
Investigators
Principal Investigator
Professor P Williams, Energy Resources Research Unit, University of Leeds
Industrial Collaborator
Project Contact, Onyx Sheffield Ltd
Project Contact, Varian Ltd
Project Contact, Quadram Institute Bioscience
Web Site
Objectives
Abstract
Dioxins (polychlorinated dibenzodioxins - PCDD) and furans (Polychlorinated dibenzofurans - PCDF) are organic micropollutants which are known to occur at trace levels in waste incinerator flue gases. There is considerable concern from the public and environmental groups surrounding the issue of dioxins and furans in the environment due to their perceived associated extreme health hazard. The control strategies being developed to minimise or eliminate PCDD/F from waste incinerator flue gas emissions are centered on operational and process controls such as combustion control, rapid cooling of flue gases, the use of additives such as activated carbon, catalytic systems for PCDD/F removal etc. However, it has been shown that there is a 'memory effect' associated with PCDD/F emissions from waste incinerators, where desorption of previously adsorbed PCDD/F from flyash in the incinerator system can take place over several days. Consequently, it is difficult to estimate the effectsof control strategies implemented for PCDD/F minimisation and can also lead to misinterpretation of results. This proposal seeks to investigate the desorption of PCDD/F from flyash under conditions typical of those found in waste incineration systems. The influence of flyash composition and PCDD/F congener profiles are also to be investigated
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Added to Database
01/01/07